Selection of Thermal Spray Coating Materials

Selecting the right coating material is a critical step in ensuring that the coating achieves the desired performance. When choosing a coating material, one must first take into account the service conditions of the workpiece and the specific properties required for the coating. Additionally, factors such as the material of the workpiece, production batch size, cost-effectiveness, and the thermal spraying method to be employed should also be considered. According to their functions, coatings can generally be categorized into corrosion-resistant coatings, wear-resistant coatings, friction-reducing and sealing coatings, high-temperature thermal barrier coatings, insulating or conductive coatings, and dimension-repair coatings.

The failure of coated workpieces during service is often not caused by a single factor; therefore, there is not necessarily a simple relationship between meeting operational condition requirements and achieving the desired coating performance. It is essential to conduct a detailed analysis of the operational conditions and, based on reference literature or experimental data, comprehensively evaluate the coating’s structural, physical, chemical, and mechanical properties in order to identify one or more suitable coating materials.

Wear-resistant coatings are one of the primary application areas of surface coating technology. Although there is a rough correlation between coating hardness and wear resistance, hardness alone cannot fully characterize the wear resistance of a surface coating. This is because different types of wear impose varying requirements on material performance, and wear is often accompanied by additional factors such as impact, corrosion, fatigue, and temperature.

When selecting surface coating materials, one should not blindly pursue high-performance or high-priced coatings, which could lead to unnecessary waste. Moreover, the cost of a material should never be the sole criterion for determining its quality. Instead, under the premise of meeting the operational requirements, one should, whenever possible, opt for cost-effective coating materials—this is especially important in mass production. For example, if a nickel-based alloy coating can suffice, there is no need to use a cobalt-based alloy coating.

When selecting surface coating materials, you can generally follow these steps:

(1) Analyze operating conditions and part performance to understand the failure mechanisms and the requirements for coating performance.

(2) List the available coating materials;

(3) Analyze the compatibility between the candidate materials and the matrix material, as well as the thermal spraying methods that can be employed.

(4) Conduct laboratory or field tests as necessary;

(5) Determine the coating material by comprehensively considering service life, cost, and plant conditions.

(6) Determine the surface coating method and develop the coating process.

The following provides a brief introduction to the commonly used coating properties, offering guidance for selecting the appropriate spraying process.

Generally speaking, the main purposes of using thermal spray coatings are as follows:

(1) Corrosion-resistant coating;

(2) Wear-resistant coating;

(3) Friction-reducing and sealing coatings;

(4) High-temperature thermal barrier coatings;

(5) Insulating or conductive coatings;

(6) Dimensional repair coatings, and so forth.

Different purposes should call for different coatings.

1. Corrosion-resistant coating

The selection of corrosion-resistant coating materials is quite complex. The operating conditions, working temperature, working environment, and various corrosive media of the part all increase the requirements for coating materials. The corrosive environment may involve aqueous solutions, gases, or a variety of chemical media, and it may also span a wide temperature range. Under conditions where combustible gases are present, combustion gases or unburned fuels can, at appropriate temperatures, react with other substances to create highly complex corrosive environments. In essence, there are three primary mechanisms underlying corrosion prevention:

(1) Exclude corrosive environments. This primarily relies on coatings that are impermeable to corrosive media and do not react with them.

(2) Preventing electrochemical corrosion. This involves leveraging the properties of the substrate metal and coating material—specifically, their oxidation-reduction potentials—to determine whether the coating acts as a cathode or an anode relative to the substrate, as well as to ascertain the coating’s electrode potential. If the coating and substrate materials are improperly matched, electrochemical corrosion may occur. The following table lists the standard electrode potentials of certain metallic elements at 25°C.

The standard electrode potentials of certain metallic elements in aqueous solutions at 25°C.

(3) Inhibiting corrosion. By using chemical corrosion inhibitors as sealants in spray coatings, certain protective effects can be achieved. This approach involves either saturating porous spray coatings with corrosion inhibitors or filling them with inorganic sealants. With thinner coatings, it is possible to meet the requirement of completely repelling corrosive environments. In some cases, corrosion-resistant metals can also serve as anti-corrosion coatings; however, most commonly, oxide ceramics are used as anti-corrosion coatings.

The main types of corrosion-resistant coatings are as follows:

(1) Atmospheric corrosion-resistant coating

This type of coating is resistant to corrosion under the following conditions: metals or alloys exposed to outdoor or indoor atmospheric environments—but not immersed in liquids. In the atmosphere, the coating can effectively withstand corrosion caused by wind, rain, sunlight, and other climatic variations. All quality assessments are based on results obtained from outdoor exposure. Coatings designed for outdoor use also perform well indoors.

These types of coatings include:

a. Industrial-atmosphere-resistant coating. This coating can withstand harsh atmospheric conditions characterized by soot or chemical fumes (such as those found in large cities and heavy industrial zones).

b. Coatings resistant to marine atmospheric corrosion. These coatings can withstand corrosion in environments near the ocean or under conditions characterized by salt spray—environments that are highly saline and humid.

c. Coatings resistant to atmospheric corrosion in rural areas. Although the rural atmosphere lacks industrial smog and salt spray typical of marine climates, it does contain trace amounts of pollutants.

(2) Immersion-resistant corrosion coating

Immersion corrosion occurs when a metal or its coating is exposed to a liquid and subjected to immersion—either wholly, partially, or in alternating cycles. The anticorrosive coating must be able to withstand corrosion in environments both above and below the liquid surface. Such coatings include the following types:

a. A coating that is resistant to freshwater consumption. This coating is resistant to freshwater and does not alter the chemical composition of the water, ensuring it remains safe for consumption.

b. Coating resistant to non-potable freshwater. This coating is resistant to non-potable freshwater with a water temperature not exceeding 52°C and a pH range of 5 to 10.

c. Heat-resistant freshwater coating. This water-based coating is not intended for drinking; the water temperature ranges from 52 to 204 °C, and the pH value is between 5 and 10.

d. Saltwater corrosion-resistant coating. This coating can be fully or partially immersed in static or flowing brine or seawater.

e. Coatings used in the chemical and food industries. These coatings are resistant to chemical agents such as oils, fuels, and solvents, as well as to corrosion from various foods; however, they do not alter the chemical composition or taste of the food.

The two aforementioned corrosion-resistant coatings can be prepared by arc spraying (including high-velocity arc spraying) or flame spraying zinc or aluminum.

(3) Chemical-resistant coating

These coatings can withstand corrosion from a variety of acidic, alkaline, and saline solutions, as well as from vapors and solids. The coatings primarily consist of various iron-based, nickel-based, and cobalt-based alloys, self-fluxing alloys, non-ferrous metals, oxide ceramics, chromium carbide, and tungsten carbide—metal-ceramic composites. Since thermal spray coatings all have a certain porosity, it is essential to perform filling and sealing treatments on these coatings. Moreover, the sealants themselves must also be resistant to corrosion by chemical media.

2. Wear-resistant coating

Part wear is typically accompanied by a rise in temperature, which may be caused either by friction or related to the operating environment. In general, wear-resistant coatings are applied under conditions involving impact wear or in corrosive environments. Therefore, as wear-resistant coatings, they must be hard, resistant to fracture, and possess certain levels of thermal resistance as well as resistance to corrosion by chemical media. Many carbides, nitrides, oxides, nickel-based alloys, and cobalt-based alloys all exhibit these properties.

Due to differences in the operating environment, working temperature, and wear conditions, the wear patterns are relatively complex. Summarized, there are four main types of wear:

(1) Adhesive wear: This wear-resistant coating is primarily used as a surface for both soft and hard bearings.

a. Soft bearing surface. This coating allows abrasive particles carried by the lubricant to become embedded within the coating, and it can also cause deformation of the reference lines on the bearing surface. Soft bearings are less expensive, but they require excellent lubrication; otherwise, wear will occur too rapidly.

b. Hard bearing surfaces. This coating can be used as a highly wear-resistant and hard bearing material, offering excellent resistance to abrasive wear, reducing scratches and scarring, and suitable for hard bearing surfaces operating under high loads at low speeds.

(2) Abrasive wear

a. Coatings resistant to abrasive particle wear. These coatings can withstand the cutting and grooving effects of foreign particles between sliding surfaces; therefore, the coating’s hardness is greater than that of the abrasive particles themselves. For coatings used at high temperatures, the operating temperature ranges from 540 to 845°C; for coatings used at low temperatures, the operating temperature is below 540°C.

b. Hard-face wear-resistant coatings. These coatings are capable of withstanding sliding wear on hard surfaces or soft surfaces containing hard abrasives. The coating must be smooth to minimize the degree of wear and should also have an appropriate coefficient of friction. Coatings used at high temperatures operate within a temperature range of 540 to 845°C, while coatings used at low temperatures operate below 540°C. Among the hard-face wear-resistant coatings used at low temperatures, there are also coatings designed to resist wear from fibers and textile threads.

(3) Surface fatigue wear

a. A coating resistant to orienteering wear. This coating can withstand wear caused by sliding, rolling, or impact on the track and is sufficiently durable to endure continuous impact abrasion.

b. Coatings resistant to wear caused by random motion. These coatings can withstand vibrational friction arising from small displacements between contacting surfaces. Since the contact friction system involves random motion, the wear pattern of the coating is highly unpredictable; vibration is the most common phenomenon associated with this type of wear. Such coatings are further categorized into two types: those designed for use at high temperatures and those designed for use at low temperatures.

c. Cavitation-resistant coating. This coating can withstand mechanical impact wear caused by cavitation in liquid flows and features high toughness, excellent wear resistance, and superior corrosion resistance.

(4) Erosive wear

This coating is resistant to erosion caused by sharp and hard particles—particles that are transported by gases or liquids and move at a certain velocity. When the erosion angle of the particles is less than 45°, the particles fly along the surface, resulting in abrasive wear. In such cases, the primary requirement for the coating is its hardness. However, when the erosion angle exceeds 45°, the coating’s toughness becomes the key factor. This coating is available in two types, suitable for use under both high-temperature and low-temperature conditions.

3. Mechanical Part Clearance Control Coating (Wear-Resistant Sealing Coating)

The mechanical efficiency of a machine driven by gas under pressure depends on the sealing capability of its rotor. High sealing capability can minimize or even prevent gas leakage; therefore, it is essential to maintain an extremely tight clearance between the rotor and the stator. Since rotating parts may expand or elongate under operating conditions and potentially come into contact with stationary parts, it is challenging to manufacture machines with such tight clearances. However, this issue can be effectively addressed by using a wearable sealing layer. The method involves spraying a wearable sealing coating onto the stationary part. As the rotating components move, they gradually wear down the coating, thereby forming a tightly fitting sealing channel with precise dimensions.

Typical abradable coatings are used on the compressor and turbine casings of jet engines. The coating should be sufficiently thick to allow for overlap between the rotor blades and the casing during engine assembly. When the engine starts, the blade tips rub against the coating, gradually wearing away some of the coating material and forming channels—while the blades themselves remain undamaged. Because the coating accommodates both radial and axial movements of the blades, each blade tip can achieve optimal sealing within the coating. When designing abradable coatings, it is essential to address two fundamentally opposing requirements: the coating must not only be abradable but also resistant to erosion caused by airflow and particle impact. Therefore, it is necessary to carefully balance the coating’s abradability against its resistance to erosion, as well as its thermal stability and resistance to chemical corrosion. The following table lists several commonly used abradable sealing coating materials along with their respective performance characteristics.

4. High-temperature thermal barrier coating

(1) High-temperature resistant coatings—these coatings can enhance the high-temperature operating conditions of substrate components and withstand chemical or physical degradation, as well as chemical damage caused by corrosion, under high-temperature conditions.

(2) Atmospheric oxidation-resistant coating. This type of coating prevents damage to the substrate caused by high-temperature oxidation. The coating has a melting point higher than the operating temperature and exhibits low vapor pressure at the operating temperature. The coating is not required to withstand mechanical wear.

(3) Gas-corrosion-resistant coatings. These coatings protect the substrate by shielding it from exposure to high-temperature corrosive gases. When considering reactions between the gas and the coating, it is essential to prevent the formation of adsorbed oxides, brittle phases, or components that could penetrate the coating and erode the substrate. Such coatings are not required to withstand mechanical impacts or wear.

(4) High-temperature (above 850°C) erosion-resistant coatings. These coatings must not only withstand high temperatures but also resist particle erosion. At high temperatures, high-speed particles and high-pressure gases create a variety of harsh environments; therefore, the coating must be able to endure erosion caused by moving, sharp, and hard particles. When the particle impact angle is less than 45°, the particles cause abrasive wear along the surface, so the coating must have high hardness. When the particle impact angle exceeds 45°, the coating must exhibit high toughness.

(5) Thermal barrier coatings. These coatings exhibit low thermal conductivity, which helps prevent the substrate material from reaching its melting point and also serves to redirect radiant heat.

(6) Molten-metal-resistant coatings: These coatings can withstand corrosion by molten metals and do not exhibit wetting behavior toward them. Examples include coatings resistant to molten zinc, aluminum, steel, iron, and copper.

5. Electrical insulation